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Magnetic resonance raman optical activity of ferrocytochrome e at different laser wavelengths

✍ Scribed by L.D. Barron

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 255 KB
Volume: 46
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80656-8

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✦ Synopsis

Magnetic field induced resonance Ramdn circular intensity differentId spectra arc rcportcd for the two argon ian 1~s~ wavelengths (514.5 and 501.7 nm) that fall withm the p electronic absorption band of fcrrocytochrome c. The Ggna and magnitudes of the effects arc completely different in the t&o sets of spectra, and mght be related to the slope of tkc COF~(Isponding magnetic circvler dlchroism band envelope at the excitation wavelength.

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## Abstract The theory of magnetic resonance Raman optical activity in metal porphyrins is developed. Irreducible tensor methods are used to calculate the transition polarizabilities (involving both symmetric and antisymmetric contributions) which are formulated in terms of a vibronic development o