Luminescent platinum(II) bis(1,1-dithiolate) complexes
✍ Scribed by Scott D. Cummings; Richard Eisenberg
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 816 KB
- Volume
- 242
- Category
- Article
- ISSN
- 0020-1693
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📜 SIMILAR VOLUMES
## A single crystal ESR study of [Cu(i-h!NT),] (Bu,NIs diluted in the corresponding nickel complex is reported-Using an hI0 model of D4h symmetry, the bonding parameters of the first coordination sphere were calculated. The influence of the ligand spin-orbit interaction is considered. ,
In the title compound, (C 4 H 12 N) 2 [Cu(C 3 S 5 ) 2 ], the Cu II atom lies on a centre of inversion and is coordinated by four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry.
In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.
In the title compound, (C 7 H 10 N) 2 [Zn(C 3 S 5 ) 2 ], the Zn II ion is located on a twofold axis and coordinated by four 2-thioxo-1,3-dithiole-4,5-dithiolate S atoms with a distorted tetrahedral geometry. The asymmetric unit contains two independent Nethylpyridinium cations, each having mirror sy