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Low valence states of metal chelates—II: Bis(2,2′,2″-terpyridine) iron(II) perchlorate

✍ Scribed by S. Musumeci; E. Rizzarelli; S. Sammartano; R.P. Bonomo

Book ID: 118910450
Publisher: Elsevier Science
Year: 1974
Weight: 345 KB
Volume: 36
Category: Article
ISSN: 0022-1902
DOI: 10.1016/0022-1902(74)80825-0

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In the title complex, [Mn(C 22 H 17 N 3 ) 2 ](ClO 4 ) 2 , the MnN 6 coordination geometry is distorted octahedral, involving the six N atoms of two 4 0 -(4-methylphenyl)-2,2 0 :6 0 ,2 00 -terpyridine (ttp) ligands. The two chelated ttp planes are almost perpendicular, with a dihedral angle of 89.1 (