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Low valence states of metal chelates. VII. Bis[bis(2′-quinolyl)-2,6-pyridine]iron(II) perchlorate

✍ Scribed by R.P. Bonomo; S. Musumeci; E. Rizzarelli; S. Sammartano


Book ID
114041546
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
561 KB
Volume
11
Category
Article
ISSN
0020-1693

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Lattice trapping of metastable quintet s
✍ Harold A. Goodwin; Kristian H. Sugiyarto 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 393 KB

The 'Tz% 'A, spin transition in [ Fe( bpp),][ BF412 (bpp= 2,6-bis( pyrazol-3-yl)pyridine) is abrupt and complete and shows hysteresis with the transition temperatures r,r = 173 K and T,t = 183 K. Rapid cooling of the sample causes the freezing-in of metastable quintet state species at low temperatur