In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two __N__-donor thiocyanate anions and two __N__-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands
Low-temperature structures of catena-(bipyrimidine-N,N')bis(thiocyanato)copper(II) and poly-(μ-bipyrimidine-N,N',N'',N''')tetrakis(thiocyanato)dicopper(II)
✍ Scribed by De Munno, G. ;Bruno, G. ;Nicolò, F. ;Julve, M. ;Real, J. A.
- Book ID
- 114509684
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 457 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
In the title compound, [Cu(NCS)~2~(C~5~H~14~N~2~)]~__n__~, the Cu^II^ atom is five-coordinated in a square-pyramidal geometry, with two N atoms of the __N__,__N__-dimethylpropane-1,3-diamine ligand and two N atoms from two thiocyanate ligands defining the basal plane, and one S atom of another thioc
The title compound, [Cu(NCS) 2 (C 6 H 16 N 2 )] n , is a thiocyanatebridged polynuclear copper(II) complex. The Cu II atom is five-coordinate in a square-pyramidal geometry, with two N atoms of the N,N-diethylethane-1,2-diamine ligand and two N atoms from two thiocyanate ligands defining the basal p