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‘Low-temperature method’ for a dramatic improvement in enantioselectivity in lipase-catalyzed reactions

✍ Scribed by Takashi Sakai

Book ID
108283821
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
428 KB
Volume
15
Category
Article
ISSN
0957-4166

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📜 SIMILAR VOLUMES

Low-temperature method for enhancement o
Low-temperature method for enhancement of enantioselectivity in the lipase-catalyzed kinetic resolutions of solketal and some chiral alcohols
✍ Takashi Sakai; Tetsuo Kishimoto; Yukie Tanaka; Tadashi Ema; Masanori Utaka 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 223 KB

Low-temperature method (--40 \*C at best) for enhancement of the enantioselectivity in a lipase-catalyzed transesterification was proved to be widely applicable to primary and secondary alcohols and enabled theoretical prediction of the course of enhancement of the enantioselectivity physicochemical

Improvement (5-fold) of enantioselectivi
Improvement (5-fold) of enantioselectivity for lipase-catalyzed esterification of a bulky substrate at 57°c in organic solvent
✍ Yoshitaka Yasufuku; Shinichi Ueji 📂 Article 📅 1996 🏛 Springer-Verlag 🌐 English ⚖ 257 KB

A reaction temperature at S7OC produced an improvement of lipase's enantioselectivity for an esterification of a bulky substrate, such as 2-(2-methyl-or 4-trrr-butyl-phenoxy)propionic acid. in organic solvent with a suitable amount of water added. although the poor enantioselectivity was observed fo