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Low-temperature method for enhancement of enantioselectivity in the lipase-catalyzed kinetic resolutions of solketal and some chiral alcohols

✍ Scribed by Takashi Sakai; Tetsuo Kishimoto; Yukie Tanaka; Tadashi Ema; Masanori Utaka

Book ID: 104260022
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 223 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01747-x

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✦ Synopsis

Low-temperature method (--40 *C at best) for enhancement of the enantioselectivity in a lipase-catalyzed transesterification was proved to be widely applicable to primary and secondary alcohols and enabled theoretical prediction of the course of enhancement of the enantioselectivity physicochemically.

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