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Lipase-catalyzed resolution of chiral 2-amino 1-alcohols

✍ Scribed by Francalanci, Franco; Cesti, Pietro; Cabri, Walter; Bianchi, Daniele; Martinengo, Tiziano; Foa, Marco

Book ID
120217449
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
541 KB
Volume
52
Category
Article
ISSN
0022-3263

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Lipase-catalyzed resolution of primary a
Lipase-catalyzed resolution of primary alcohol containing quaternary chiral carbon
✍ Chan Seong Cheong; Dai Sig Im; Jiyoung Kim; In O Kim πŸ“‚ Article πŸ“… 1996 πŸ› Springer Netherlands 🌐 English βš– 279 KB

2-Cyano-2-phenyl-I-hexanol containing chiral quatemary carbon was resolved using a lipase. Among various reaction conditions, transesterification reaction (solvent; n-hexane, lipase; Candida cylindracea) gave high selectivity(20/80). Additionally, the selectivity could be improved( 13187) when pyrid