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Lipase-Catalyzed Kinetic Resolution of Aryltrimethylsilyl Chiral Alcohols

✍ Scribed by Palmeira, Dayvson J.; Abreu, Juliana C.; Andrade, Leandro H.

Book ID
115500374
Publisher
Molecular Diversity Preservation International
Year
2011
Tongue
English
Weight
243 KB
Volume
16
Category
Article
ISSN
1420-3049

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Lipase-catalyzed resolution of primary alcohol containing quaternary chiral carbon
✍ Chan Seong Cheong; Dai Sig Im; Jiyoung Kim; In O Kim πŸ“‚ Article πŸ“… 1996 πŸ› Springer Netherlands 🌐 English βš– 279 KB

2-Cyano-2-phenyl-I-hexanol containing chiral quatemary carbon was resolved using a lipase. Among various reaction conditions, transesterification reaction (solvent; n-hexane, lipase; Candida cylindracea) gave high selectivity(20/80). Additionally, the selectivity could be improved( 13187) when pyrid