✦ LIBER ✦

Ligating properties of model bioheterocyclics. Ill. Synthesis and characterization of the palladium(II) and platinum(II) Complexes with 3,6-disubstituted-2,7-dihydro-1,4,5-thiadinzepine derivatives

✍ Scribed by S.S. Sandhu; S. Tandon; H. Singh

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 572 KB
Volume: 34
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)94681-4

No coin nor oath required. For personal study only.

✦ Synopsis

Palladium(D) and platinum(II) halides with 3,6disubstituted-2,7dihydro-1,4,5thiadiazepine derivatives (L) form complexes of general formula, [MX,*L'] (L' = monohydrazone, VII). During the formation of these complexes, the thiadiazepine ring underwent hydrolytic cleavage at the carbonnitrogen double bond, the nitrogen of which is involved in coordination with the metal ions. These complexes have also been obtained from monohydrazones of 2,2"-thiodiacetophenones. These are diamagnetic and nonelectrolytes.

From their ir, n.m.r., electronic spectra, T.G.A., D.T.A., magnetic susceptibility and conductivity measurements, these complexes have been assigned a square planar structure.

📜 SIMILAR VOLUMES

Electrochemical reduction of the bis(1,2

Electrochemical reduction of the bis(1,2,6,7-tetracyano-3,5-dihydro-3,5-diimino-pyrrolizinido) palladium (II) complex: syntheses and properties of its radical monoanion as the tetraethylammonium salt

✍ Alberto Flamini; Nicola Poli; Alessia Panusa 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 350 KB

Tetraphenylrac-3,3,7,7-Tetramethyl-trans

Tetraphenylrac-3,3,7,7-Tetramethyl-trans-5 palladatricyclo[4.1.0.02,4]-heptane-1,2,4,6-tetracarboxylate: A New PTH Derivative and the First X-ray Crystallographic Study of a Bis(acetone)palladium(II) Complex

✍ Hashmi, A. Stephen K. ;Naumann, Frank ;Bats, Jan W. 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 328 KB 👁 1 views

On the Spectral Similarities between 1,2

On the Spectral Similarities between 1,2,6,7-Tetracyano-3,5-dihydro-3,5-diiminopyrrolizinato Complexes and Phthalocyanines – X-ray Crystal and Molecular Structure of Two Mixed Monopyrrolizinato Nickel(II) Complexes with the 2,4-tert-Butylacetylacetonide Ligand

✍ Alberto Flamini; Vincenzo Fares; Augusto Pifferi 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 414 KB 👁 1 views

Complexes of Ni II , Cu II , Zn II , and Co III containing the 1,2,6,7tetracyano-3,5-dihydro-3,5-diiminopyrrolizinide (L) and the 2,4-tert-butylacetylacetonide (DPM) ligands have been synthesized and characterized. The absorption optical spectra of these species and of the corresponding ML 2 complex

Synthesis, Characterization, and DNA-Bin

Synthesis, Characterization, and DNA-Binding Properties of the Ruthenium(II) Complexes [Ru(dipn)(dptp)](ClO4)2 and [Ru(dipn)(pat)](ClO4)2 (dipn=N-(3-Aminpropyl)propane-1,3-diamine; dptp=2-(5,6-Diphenyl-1,2,4-triazin-3-yl)-1,10-phenanthroline; pat=9-(1,10-Phenanthrolin-2-yl)acenaphtho[1,2-e][1,2,4]triazine)

✍ Xian-Lan Hong; Hui Chao; Li-Jun Lin; Kang-Cheng Zheng; Hong Li; Xiang-Li Wang; F 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 German ⚖ 253 KB 👁 1 views

## Abstract Two novel tridentate ruthenium(II) complexes containing an asymmetric heteroaromatic and a polyamine ligand, [Ru(dipn)(dptp)](ClO~4~)~2~ (**1**⋅2 $\rm{ ClO\_4^ -}$) and [Ru(dipn)(pat)](ClO~4~)~2~ (**2**⋅2 $\rm{ ClO\_4^ -}$) (dipn=__N__‐(3‐aminopropyl)propane‐1,3‐diamine; dptp=2‐(5,6‐dip