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Electrochemical reduction of the bis(1,2,6,7-tetracyano-3,5-dihydro-3,5-diimino-pyrrolizinido) palladium (II) complex: syntheses and properties of its radical monoanion as the tetraethylammonium salt

โœ Scribed by Alberto Flamini; Nicola Poli; Alessia Panusa


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
350 KB
Volume
247
Category
Article
ISSN
0020-1693

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## Palladium(D) and platinum(II) halides with 3,6disubstituted-2,7dihydro-1,4,5thiadiazepine derivatives (L) form complexes of general formula, [MX,*L'] (L' = monohydrazone, VII). During the formation of these complexes, the thiadiazepine ring underwent hydrolytic cleavage at the carbonnitrogen doub