Substituted 2-methylsulfinyl pyridines react with Grignard reagents to afford 6,6'-disubstituted-2,2 '-bipyridines (substituents: MeS, Cl, Br, H) in fair yields. Recently, we have shown that the reaction of benzyl 2-pyridyl sulfoxide with Grignard reagents or organolithium reagents gives intramolecu
✦ LIBER ✦
LIGAND EXCHANGE AND LIGAND COUPLING VIA THE σ-SULFURANE INTERMEDIATE IN THE REACTION OF ALKYL 2-PYRIDYL SULFOXIDE WITH GRIGNARD REAGENTS: CONVENIENT PREPARATION OF 2,2′-BIPYRIDINES
✍ Scribed by Oae, Shigeru; Kawai, Tsutomu; Furukawa, Naomichi
- Book ID
- 115529013
- Publisher
- Informa UK (Taylor & Francis)
- Year
- 1987
- Weight
- 588 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0308-664X
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