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Laser Induced Fluorescence Spectrum of theA2Π–X2Σ (1,1) Band of ZrN

✍ Scribed by C.M-T. Chan; Haiyang Li; N.S-K. Sze; A.S-C. Cheung

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
135 KB
Volume
180
Category
Article
ISSN
0022-2852

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✦ Synopsis

The A 2 P-X 2 S (1,1) band of ZrN between 5642 and 5879 A ˚has been studied using laser induced fluorescence spectroscopy. ZrN was produced by reacting vaporized ZrCl 4 with microwave discharged N 2 gas. All the 12 branches expected from a 2 P-2 S transition have been observed and assigned. Various perturbations in the 2 P 3/2 substate £ Å 1 level have been found, in which the one at J Å 38.5 is ascribed to a degenerate state. The magnetic hyperfine structure of the 91 ZrN has also been identified. A least-squares fit up to J Å 30.5 yielded molecular constants for both the A 2 P and the X 2 S states of four isotopic molecules.

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