In this work we studied the collinear F(\*P,$ + Hz system in a strong CO2 laser field. It was found that the tiajecror) surface hopping method (TSHM) yields entirely different results than the exact quantum-mechanical treatment. A curvecrossing model was devised to esplain the discrepancy.
Laser induced dielectric breakdown studies of the reaction UF6 + H2
β Scribed by A.M. Ronn; B.L. Earl
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 214 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Laser induced dielectric breakdown (LIDB) has been documented in UF6 at pressures ranging from 8-100 ton. A high power, line selectable TEA CO2 laser has been used as the source to induce the dielectric breakdown (DB). Reactions of the fragmented UFb with Hz have been studied at various pressure ratios. In all cases a rapid and large pressure drop and heavy deposits of suspended particulates were observed and attributed to the LIDB driven reaction 2UF6 + H2 * 2UF5 + 2HF.
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