𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Hot-atom initiated chemical laser study of the H* + SF6 reaction

✍ Scribed by Michael J. Berry


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
344 KB
Volume
22
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


Chemical laser methods have been used to study the "hot-atom" reaction: H* + SF6 -+ products at KE,,l < 107, kcal mole-'.

Collision-induced dissociation of SF6 by II* is the dominant reaction ci~annel.


📜 SIMILAR VOLUMES


An FTIR study of the Cl-atom-initiated r
✍ H. Niki; P. D. Maker; C. M. Savage; L. P. Breitenbach 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 564 KB

The kinetics and mechanism of C1-atom-initiated reactions of CHO-CHO were studied using the FTIR detection method to monitor the photolysis of Cl,-CHO-CHO mixtures in 700 torr of N2-0, diluent at 298 ? 2 K. The observed product distribution in the [021 pressure of 0-700 torr combined with relative r

Hot-atom—laser-induced-fluorescence expe
✍ K. Kleinermanns; J. Wolfrum 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 239 KB

The nascent rotational and fine-structure state distributions in OH (o = 0) produced in the endothermic reaction H + CO2 OH + CO have been measured with hot hydrogen atoms from the photodissociation of HBr at 193 nm. Considerable OH rotational excitation broadly peaked at around K = 11 is observed.

FTIR study of the Cl-atom initiated oxid
✍ M. Green; G. Yarwood; H. Niki 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 533 KB

## Abstract The kinetics and mechanism of Cl‐atom initiated reactions of CH~3~C(O)CHO were studied using the FTIR detection method in the photolysis (λ < 300 nm) of Cl~2~CH~3~C(O)CHO mixtures in 700 torr of N~2~O~2~ diluent at 298 ± 2 K. The observed product distribution over the O~2~ pressure ra

Laser induced dielectric breakdown studi
✍ A.M. Ronn; B.L. Earl 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 214 KB

Laser induced dielectric breakdown (LIDB) has been documented in UF6 at pressures ranging from 8-100 ton. A high power, line selectable TEA CO2 laser has been used as the source to induce the dielectric breakdown (DB). Reactions of the fragmented UFb with Hz have been studied at various pressure rat

FTIR study of the Cl- and Br-atom initia
✍ V. Catoire; P. A. Ariya; H. Niki (Deceased); G. W. Harris 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB 👁 2 views

The Cl-and Br-initiated oxidations of CHCl"CCl 2 in 700 torr of air at 296 K have been studied using a Fourier transform infrared spectrometer. Rate constants k(Cl ϩ and were determined using a relative rate technique with ethane and ethylene as Ϫ 1 Ϫ 1 molecule s references, respectively. The majo

FTIR spectroscopic study of the Cl- and
✍ G. Yarwood; N. Peng; H. Niki 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 739 KB

## Abstract The reaction mechanism of the halogen (Cl and Br)‐atom initiated oxidation of C~2~H~4~ was studied using the long path FTIR spectroscopic method in 700 torr of air at 296 ± 2 K. Among the major halogen‐containing products were XCH~2~CHO, XCH~2~CH~2~OH, and XCH~2~CH~2~OOH (X = Cl or B