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Lanthanide induced shift nmr studies of some bicyclo-[6·1·0]-nona-2,4,6-triene derivatives

✍ Scribed by Clair J. Cheer; William Rosen; J.Johnaf Uebel


Book ID
104243199
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
215 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis


The chemical behavior of bicycle-[6.1.0]-nona-2,4,6-triene and its derivatives has been the subject of many investigations.


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Reaction of cis-Bicyclo[6.1.0]nona-2,4,6
✍ Dr. Gernot Boche; Dipl.-Chem. Heinrich Weber; Jürgen Benz 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 238 KB 👁 1 views

Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres