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Electrochemical reduction studies of several bicyclo[6.1.0]nona-2,4,6-trienes and of cis-bicyclo[6.2.0]deca-2,4,6-triene. Search for a polarographic criterion of homoaromaticity

✍ Scribed by Anderson, Larry B.; Broadhurst, Michel J.; Paquette, Leo A.


Book ID
126115745
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
759 KB
Volume
95
Category
Article
ISSN
0002-7863

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Reaction of cis-Bicyclo[6.1.0]nona-2,4,6
✍ Dr. Gernot Boche; Dipl.-Chem. Heinrich Weber; JΓΌrgen Benz πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 238 KB πŸ‘ 1 views

Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres