Kinetics of the reaction of hydrogen iodide with 1,1-difluoroethylene
โ Scribed by Carlton, Terry S.; Harker, A. B.; Natale, W. K.; Needham, R. E.; Christensen, Ronald L.; Ellenson, J. L.
- Book ID
- 127280886
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 525 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The kinetics of gasโphase reaction of CH~3~CF~2~I with HI were studied from 496 to 549K and have been shown to be consistent with the following mechanism: equation image A least squares treatment of the data gave where ฮธ = 2.303 __RT__ kcal/mole. The observed activation energy __E__
The reactions of HI with OH and NO3 have been studied in discharge-flow reactors coupled to EPR and mass spectrometry for analysis, The rate constants for the reactions HI+OH+H20 t I (1) and HI t NO3 +HNO, t I (2) were determined al 298 K: k,=(3.3+0.2)xlO-" and kz = (2.5f0.8) X 10 --IS cm3 molecule-