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Kinetics of the gas phase addition of bromine to 1,1-difluoroethylene. .pi. Bond dissociation energy of 1,1-difluoroethylene

โœ Scribed by Pickard, J. M.; Rodgers, A. S.


Book ID
127261565
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
380 KB
Volume
98
Category
Article
ISSN
0002-7863

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The gas-phase kinetics of the reaction o
โœ J. M. Pickard; A. S. Rodgers ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 253 KB

## Abstract The kinetics of gasโ€phase reaction of CH~3~CF~2~I with HI were studied from 496 to 549K and have been shown to be consistent with the following mechanism: equation image A least squares treatment of the data gave where ฮธ = 2.303 __RT__ kcal/mole. The observed activation energy __E__