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Kinetics of the Reaction between Acetylperoxy and Ethylperoxy Radicals

โœ Scribed by Maricq, M. Matti; Szente, Joseph J.

Book ID
126220552
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
124 KB
Volume
104
Category
Article
ISSN
1089-5639

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๐Ÿ“œ SIMILAR VOLUMES

The reaction of acetylperoxy radicals wi
The reaction of acetylperoxy radicals with NO2
โœ Norman Basco; Sucha S. Parmar ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 593 KB

Acetylperoxy radicals were produced by the flash photolysis of chlorine in the presence of acetaldehyde and oxygen. By adding various concentrations of nitrogen dioxide, the rate constant for the reaction producing PAN was measured to be k, (153 Torr) = (2.29 ? 0.051 X The effect of pressure has be

The reaction of ethylperoxy radicals wit
The reaction of ethylperoxy radicals with NO2
โœ Hiroyuki Adachi; Norman Basco ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 337 KB

Tile rate constant for the reaction C2H502 + NO 2 ~ products (10) has been measured directly by flash photolysis and kinetic spectroscopy in the pressure range 44-676 Torr. At room temperature klo = (7.5 ยฑ 0.4) ร— 108 ~ mole -1 s -1 so that the rate of formation of the probable primary product, perox

Spectra and reactions of acetyl and acet
Spectra and reactions of acetyl and acetylperoxy radicals
โœ Norman Basco; Sucha S. Parmar ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 451 KB

The ultraviolet absorption spectra of the acetyl and acetylperoxy radicals have been Characterized in the range 195-280 nm. The acetyl radical was generated by the flash phbtolysis of Clz in the presence of CH3CH0 and was converted to the acetylperoxy radical in the presence of excess O2 The extinct