✦ LIBER ✦

Spectra and reactions of acetyl and acetylperoxy radicals

✍ Scribed by Norman Basco; Sucha S. Parmar

Publisher: John Wiley and Sons
Year: 1985
Tongue: English
Weight: 451 KB
Volume: 17
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550170809

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✦ Synopsis

The ultraviolet absorption spectra of the acetyl and acetylperoxy radicals have been Characterized in the range 195-280 nm. The acetyl radical was generated by the flash phbtolysis of Clz in the presence of CH3CH0 and was converted to the acetylperoxy radical in the presence of excess O2 The extinction coefficient of the acetylperoxy radical was measured to be 2300 L/mol cm at the maximum at 207 nm and the rate constant for the reaction 2CHSC03 -2CH3 + 2C02 + 0 2 was evaluated to be k, = (4.8 2 0.8) x lo9 L/mol s

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