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Flash photolysis of biacetyl in gas phase. Rate constants of reactions between methyl and acetyl radicals

โœ Scribed by Raimo Timonen; Kaarlo Kalliorinne; Kurt Blomqvist; Jouko Koskikallio

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
354 KB
Volume
14
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

The flash photolysis of biacetyl produces CO, CZH6, and CH3COCH3 as main products, and in small amounts COz, CzH4, and CH3CHO. The rate constants of reactions ( 2) and

of' thermally equilibrated radicals were calculated from the amounts of products:

) lo'* dm3/mol. s k 3 = (2.43 f 0.14) 1O1O dm3/mol. s

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