The flash photolysis of biacetyl produces CO, CZH6, and CH3COCH3 as main products, and in small amounts COz, CzH4, and CH3CHO. The rate constants of reactions ( 2) and of' thermally equilibrated radicals were calculated from the amounts of products: ) lo'\* dm3/mol. s k 3 = (2.43 f 0.14) 1O1O dm3/
โฆ LIBER โฆ
Rates of Reactions Between Methoxycarbonyl, Methyl and Methoxy Radicals Formed in Flash Photolysis of Dimethyl Oxalate in Gas Phase
โ Scribed by E. Hassinen; P. Riepponen; K. Blomqvist; K. Kalliorinne; J. Koskikallio
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 53 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0037-9646
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The reaction products of photolysis of acetic anhydride in gas phase at 25"C, where He or C 0 2 was present as buffer gas, were analyzed by gas chromatography. The extent of photodissociation was 52% 2 5% and the extent of intramolecular hydrogen transfer reaction producing acetic acid and ketene wa