Kinetics and Mechanism of the Acetylperoxy + HO 2 Reaction
β Scribed by Crawford, Mary A.; Wallington, Timothy J.; Szente, Joseph J.; Maricq, M. Matti; Francisco, Joseph S.
- Book ID
- 127158455
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 383 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The kinetics and mechanism of the reaction Cl Ο© HO 2 : products (1) have been studied in the temperature range 230-360 K and at total pressure of 1 Torr of helium using the discharge-flow mass spectrometric method. The following Arrhenius expression for the total rate constant was obtained either fr
Acetylperoxy radicals were produced by the flash photolysis of chlorine in the presence of acetaldehyde and oxygen. By adding various concentrations of nitrogen dioxide, the rate constant for the reaction producing PAN was measured to be k, (153 Torr) = (2.29 ? 0.051 X The effect of pressure has be