Kinetics of the Oxidative Cleavage of α-Keto Acids by Quinolinium Bichromate
✍ Scribed by S. Das; G. S. Chaubey; M. K. Mahanti
- Book ID
- 110410279
- Publisher
- Springer
- Year
- 2002
- Tongue
- English
- Weight
- 47 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0023-1584
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📜 SIMILAR VOLUMES
Photosensitized oxygenation of a-keto carboxylic acids in the presence of diazo compounds afforded the corresponding carboxylic acids and carbon dioxide in high yields; oxidative decarboxylation by carbonyl oxides occurred. Hydroxylations catalyzed by several dioxygenases require cc-keto carboxylic
The rates of oxidation of four a-keto acids, glyoxylic, pyruvic, phenylglyoxylic, and 2oxobutyric acids by Cerium(1V) in H2S04-HaHS04 and HzS04-HC104 solutions, have been studied spectrophotometrically. The rate data suggest that CeSO:' is the most reactive of the Cerium(1V)-sulfate complexes presen
OXIDATIVE CLEAVAGE OF a-DIOLS, a-DIONES, a-HYDROXY--KETONES AND a-HYDROXY-AND a-KETO ACIDS WITH CALCIUM HYPOCHLORITE [CafOCl),].