Oxidative cleavage of α-diols, α-diones, α-hydroxy-ketones and α-hydroxy- and α-keto acids with calcium hypochlorite [Ca(OCl)2].
✍ Scribed by Stephen O. Nwaukwa; Philip M. Keehn
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 226 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
OXIDATIVE CLEAVAGE OF a-DIOLS, a-DIONES, a-HYDROXY--KETONES AND a-HYDROXY-AND a-KETO ACIDS WITH CALCIUM HYPOCHLORITE [CafOCl),].
📜 SIMILAR VOLUMES
## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate
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