Kinetics and mechanism of the oxidative cleavage of ketones by quinolinium dichromate
โ Scribed by S. Das; E. R. Rani; M. K. Mahanti
- Book ID
- 110170853
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 231 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0023-1584
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๐ SIMILAR VOLUMES
The oxidation of ortho-, meta-, and para-substituted phenols by Quinolinium Dichromate (QDC) to the corresponding Quinones in aqueous acetic acid medium is first-order with respect to [QDC] and [phenol]. There is no effect of added Quinoline on rate. The reaction is acid catalyzed. A medium of low d
The oxidation of some aliphatic alcohols by quinolinium fluorochromate (QFC) in dimethyl sulfoxide leads to the formation of corresponding carbonyl compounds. The reaction is first order with respect to QFC. The reaction exhibited Michaelis-Menten type kinetics with respect to the alcohol. The react