Kinetics and mechanism of the oxidation of formic and oxalic acids by quinolinium fluorochromate
โ Scribed by Madhu Khurana; Pradeep K. Sharma; Kalyan K. Banerji
- Book ID
- 110638257
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 67 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0253-4134
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๐ SIMILAR VOLUMES
The oxidation of some aliphatic alcohols by quinolinium fluorochromate (QFC) in dimethyl sulfoxide leads to the formation of corresponding carbonyl compounds. The reaction is first order with respect to QFC. The reaction exhibited Michaelis-Menten type kinetics with respect to the alcohol. The react
The reaction between formic acid and bromine in strongly acid aqueous media at 298 K Brz + HCOOH -2 Br-+ 2 H+ + COz was studied by absorption spectrophotometry (A = 447 nm). Reaction rates, expressed as H = -d[Brz]/dt, depend on the concentrations of HCOOH (0.3-2.4M), Br2[(2.7-13.6) X 10-3M], H+ (0.