The rate constant of the reaction OH + HCI+ Hz0 + Cl was measured in a flow tube over the temperature range 224 to 460ยฐK using resonance fluorescence detection of OH. An Arrheaius expression ki = (2.0 f 0.1) X lo-'\* exp [ -(620 f 20 cal/mole)/RT] ws obtained. Stratospheric and reaction kinetic impl
Kinetics of the Gas-Phase Reaction of OH with HCl
โ Scribed by Bryukov, Mikhail G.; Dellinger, Barry; Knyazev, Vadim D.
- Book ID
- 127290971
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 185 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
Observation of the time-resolved behaviour of OH radicals produced during the modulated photolysis of mixtures of OX, HzO, HONO and Ar at 253.7 nm, has enabled direct measurements of the rate coefficient for the reaction 0H+HONO-+NOZ+H20 (2) at 11.4 Torr and in the temperature range 278-342.5 K. Th
Absolute rate constants for the gas phase reaction of OH radicals with pyrrole tk,) and thiophene ( k , ) have been measured over the temperature ranges 298-440 and 274-382 K, respectively, using the flash photolysis-resonance fluorescence technique. The rate constants obtained were independent of t