𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics of the gas-phase reaction of OH with nitrous acid

✍ Scribed by M.E. Jenkin; R.A. Cox

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
414 KB
Volume
137
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Observation of the time-resolved behaviour of OH radicals produced during the modulated photolysis of mixtures of OX, HzO, HONO and Ar at 253.7 nm, has enabled direct measurements of the rate coefficient for the reaction 0H+HONO-+NOZ+H20

(2) at 11.4 Torr and in the temperature range 278-342.5 K. The value obtained was k,=(1.80f0.36) x lo-" exp[( -390f80)lTJ cm3 molecule-' s-'.

📜 SIMILAR VOLUMES

The kinetics of the gas phase reaction o
The kinetics of the gas phase reaction of nitrous acid with ozone
✍ E.W. Kaiser; S.M. Japar 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 377 KB

Rcccivcd 1 1 Au:just 1977 ll~ kinetics ot the grlb plea reaction bctwucn 03 (0.4-15 torr) and IIN (0.002 0.005 torr) hvc been mvcsti~:.!tcti at total pressures of 20-30 torr usmg rl 1m55 spcctromcter dctcctor. No cvldcncc ofa Ilomo~cneous-hllllolc~ul,~r reation was obtarned, and upper limits to the

Kinetics of the gas phase reaction of OH
Kinetics of the gas phase reaction of OH radicals with pyrrole and thiophene
✍ Timothy J. Wallington 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 443 KB 👁 2 views

Absolute rate constants for the gas phase reaction of OH radicals with pyrrole tk,) and thiophene ( k , ) have been measured over the temperature ranges 298-440 and 274-382 K, respectively, using the flash photolysis-resonance fluorescence technique. The rate constants obtained were independent of t

Kinetics of the gas-phase reactions of O
Kinetics of the gas-phase reactions of OH radicals with a series of trimethylphenols
✍ Iustinian Bejan; Anna Schürmann; Ian Barnes; Thorsten Benter 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 399 KB 👁 2 views

## Abstract The kinetics of the reactions of hydroxyl (OH) radicals with 2,3,5‐trimethylphenol (235TMP), 2,3,6‐trimethylphenol (236TMP), 2,4,5‐trimethylphenol (245TMP), 2,4,6‐trimethylphenol (246TMP), and 3,4,5‐trimethylphenol (345TMP) have been investigated at 298 ± 2 K and atmospheric pressure of

Kinetic and product study of the gas-pha
Kinetic and product study of the gas-phase reaction of sabinaketone with OH radical
✍ Nathalie Carrasco; Benedicte Picquet-Varrault; Jean-François Doussin 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 259 KB 👁 2 views

## Abstract Sabinaketone is one major photooxidation product of sabinene, an important biogenic volatile organic compound. This article provides the first product study and the second rate constant determination of its reaction with OH radicals. Experiments were investigated under controlled condit

Kinetics of the gas-phase reaction of CF
Kinetics of the gas-phase reaction of CF3CF2CH2OH with OH radicals and its atmospheric lifetime
✍ L. Chen; K. Fukuda; N. Takenaka; H. Bandow; Y. Maeda 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 79 KB 👁 2 views

CF 3 CF 2 CH 2 OH is a new chlorofluorocarbon (CFC) alternative. However, there are few data about its atmospheric fate. The kinetics of its atmospheric oxidation, the OH radical reaction of CF 3 CF 2 CH 2 OH, has been investigated in a 2-liter Pyrex reactor in the temperature range of 298 ϳ 356 K u

Kinetics of the gas-phase reactions of O
Kinetics of the gas-phase reactions of OH radicals with alkyl nitrates at 299 ± 2 K
✍ Roger Atkinson; Sara M. Aschmann; William P. L. Carter; Arthur M. Winer 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 388 KB 👁 1 views

## Abstract Relative rate constants for the gas‐phase reactions of OH radicals with a series of alkyl nitrates have been determined at 299 ± 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 × 10^−1