Kinetics of oxidation of ferrocene by tris-1,10-phenanthrolinecobalt(III) in t-butyl alcoholwater and acetonewater mixtures
✍ Scribed by E. Pelizzetti; E. Pramauro; M.J. Blandamer; J. Burgess; N. Gosal
- Book ID
- 108328359
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 430 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The kinetics of the solvolysis of the ion trans-[Coen2N3C11' have been investigated a t several temperatures in mixtures of water with t-butyl alcohol with concentrations of the latter ranging up to 50 vol% or a mol fraction of 0.16. Values for the enthalpy and entropy of activation show sharp chang
Rate constants for base hydrolysis of the trzs-( 1,lO-phenanthroline)iron(II) cation and for solvolysis of the cis-dichlorobis(l,2-ethanediamine)cobalt(III~ cation have been measured in binary aqueous mixtures containing l,a-ethanediol, 1,2or 1,4-butanediol, 1,2-or 1,6-hexanediol, 1-propanol, or t-b
## Abstract Rates of solvolysis of complex ions [Co(3Rpy)~4~Cl~2~]^+^ with R = __Me__ and __Et__ have been determined in mixtures of water with __t__‐butyl alcohol over a range of temperatures. Extrema found in the enthalpy Δ__H__\* and entropy Δ__S__\* of activation are correlated with the physica