Kinetics and mechanism of oxidation of arsenic(III) by ferriccyanide in methanol-water mixtures
β Scribed by Ahmed A. Abdel-Khalck
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 286 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
Diperiodatoargentate(III) oxidizes nitrilotriacetic acid in a mildly basic medium to produce formaldehyde and ammonia. This reaction follows a complex kinetic behaviour. The axial binding of NTA to silver(III) complex takes place on the millisecond time-scale with a second-order rate constant of (4.
The kinetics of the reaction between glycolaldehyde (GA) and tetrachloroaurate(III) in acetic acid-sodium acetate buffer has been studied. The reaction is first-order with respect to as well as [GA]. Both and ions retard the rate of reaction. III Ο© Οͺ Οͺ [Au ] H Cl AuCl , 4 and are the reactive specie