## Abstract The mechanism by which an excess of iron(II) ion reacts with aqueous chlorine dioxide to produce iron(III) ion and chloride ion has been determined. The reaction proceeds via the formation of chlorite ion, which in turn reacts with additional iron(II) to produce the observed products. T
The kinetics and mechanism of oxidation of octaethylporphinatosilver(II) by iron(III) perchlorate in chloroform-methanol solution
β Scribed by David J. Morano; Henry N. Po
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 206 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0020-1693
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π SIMILAR VOLUMES
The copper-catalyzed oxidation of hydrazine by iron(II1) in acid solution follows the rate law -d[Fe(III)]/dt = ~K~[CU(II)]~/(K~ + [H+]), where Kh is the hydrolysis constant of Cu2+, k was found t o be 8.8f0.8, 13.2f1.4 and 17.5f1.3 min-' at 35, 40, and 45OC respectively and p= 0.2 mol/L. The compos
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