## Abstract The oxidation of halotoluenes by hexacyanoferrate(III) in aqueous acetic acid containing perchloric acid (0.5__M__) at 50Β°C gave the corresponding aldehyde as the major product, and a small amount of polymeric material. The order with respect to each of the reactantsβsubstrate, oxidant,
Kinetics and mechanism of the oxidation of glutathione by hexacyanoferrate(III) in aqueous solution
β Scribed by G. Stochel; P. Martinez; R. van Eldik
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 579 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0162-0134
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π SIMILAR VOLUMES
Kinetics of oxidation of phenylhydrazine and p-bromophenylhydrazine by hexacyanoferrate(I1If in acidic medium have been studied. The reactions follow similar kinetics, being first order with respect to both hydrazine and hexacyanoferrate(II1) and inverse first order with respect to the hydrogen ion.
The kinetics of oxidation of methyl cellulose polysaccharide as a natural polymer by alkaline potassium ferricyanide at a constant ionic strength of 1.0 mol dm -3 have been studied, spectrophotometrically. The experimental results showed complex kinetics where the pseudo first-order plots were found
## Abstract A kinetic study of the oxidation of allyl alcohol by potassium hexacyanoferrate (III) in the presence of palladium (II) chloride is reported. The reaction was observed by measuring the disappearance of the potassium hexacyanoferrate (III) spectrophotometrically. The reaction is first or
The hexacyanoferrate(II1)-thallium(1) reaction in aqueous acetic acid containing large concentrations of hydrochloric acid is considerably accelerated both by hydrogen and chloride ions as well as increasing acetic acid in the medium. The experimental results obey the rate law (1) where PI to p6 (1
The reaction between tetrachloroaurate(III) and malonic acidfmalonate ion was studied kinetically over a wide range of temperatures, malonate, hydrogen and chloride ion concentrations at ionic strength 1.0 M. The suggested reaction mechanism consists of a series of substitution reactions during whic