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Kinetics and mechanism of palladium (II) chloride catalyzed oxidation of allyl alcohol by potassium hexacyanoferrate (III)

✍ Scribed by Iftikhar Ahmad; C. Muhammad ashraf

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 243 KB
Volume: 11
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550110802

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✦ Synopsis

Abstract

A kinetic study of the oxidation of allyl alcohol by potassium hexacyanoferrate (III) in the presence of palladium (II) chloride is reported. The reaction was observed by measuring the disappearance of the potassium hexacyanoferrate (III) spectrophotometrically. The reaction is first order with respect to allyl alcohol and palladium (II) chloride, inverse second order with respect to [Cl^−^], and zero order with respect to potassium hexacyanoferrate (III). The rate is found to increase linearly with hydroxyl ion concentration.

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