Kinetics of substitution on chloro-1,1,7,7-tetraethyldiethylene-triaminegold(III) in methanol-water mixtures
โ Scribed by Roger D. Alexander; Paul N. Holper
- Publisher
- Springer
- Year
- 1980
- Tongue
- English
- Weight
- 291 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0340-4285
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๐ SIMILAR VOLUMES
The kinetics of the solvolysis of the ions [Co(NH3)sC1 ] 2 + and [Co(CN)sC1] 3-have been investigated in a range of water-rich mixtures of water with n-PrOH at various temperatures. The variation of the enthalpies and entropies of activation with solvent composition show extrema in composition range
The kinetics of the reaction between l-chloro-2,4-dinitrobenzene and piperidine was studied in several completely non-aqueous binary solvent mixtures where the preferential solvation is the rule at 15,Z and 40 "C. The reaction was chosen as the simplest example of aromatic nucleophilic substitution