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Kinetics of O·− and O3·− in alkaline aqueous solutions of hydrogen peroxide

✍ Scribed by Mónica C. Gonzalez; Daniel O. Mártire

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
185 KB
Volume
29
Category
Article
ISSN
0538-8066

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✦ Synopsis

The photolysis of strong alkaline solutions of H 2 O 2 yields , which in the presence of molecular oxygen forms the ozonide radical ion,

. A detailed kinetic study on the reaction mechanisms involved during formation and decay of radical ions in these solutions, in the presence and absence of added scavengers is reported. In order to obtain a complete interpretation of the experimental data, kinetic computer simulations were done using a complete set of reactions. A very good agreement between experimental and computer simulated data is obtained. The following simplified mechanism accounts for the observed first-order decay of in alkaline hydrogen peroxide solutions:

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