๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

ChemInform Abstract: Kinetics and Mechanism of the Pyridinolysis of O-Ethyl S-Aryl Thiocarbonates in Aqueous Solution.

โœ Scribed by E. A. CASTRO; M. I. PIZARRO; J. G. SANTOS

Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
28
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Kinetics and mechanism of the aminolysis
Kinetics and mechanism of the aminolysis of O-ethyl S-aryl thiocarbonates in acetonitrile
โœ Hyuk Keun Oh; Yun Ho Lee; Ikchoon Lee ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 51 KB ๐Ÿ‘ 2 views

The kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0ะŠC are studied. Relatively small values of โค X (โค nuc ) ฯญ 0.6 ฯณ 0.8 and โค Z (โค lg ) ฯญ ฯช0.5 ฯณ ฯช0.7 together with a negative cross-interaction constant XZ (ฯญ ฯช0.47) and failure o

Kinetics and mechanism of the aminolysis
Kinetics and mechanism of the aminolysis of O-ethyl S-aryl dithiocarbonates in acetonitrile
โœ Hyuck Keun Oh; Jun Yong Lee; Jeong Hwan Yun; Young Sook Park; Ikchoon Lee ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 139 KB ๐Ÿ‘ 2 views

The aminolysis reactions of O-ethyl S-(Z-phenyl) dithiocarbonates ( H, Z ฯญ p-CH , 3 p-Cl, and p-NO 2 ) with anilines (AN) and N,N-dimethylanilines (DMA) in acetonitrile at 30.0ะŠC are investigated. Relatively small values of and for โค (โค ,0.4 ca. 0.7) โค (โค ฯช0.1 ca. ฯช0.4) X n u c Z l g both ANs and DM