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ChemInform Abstract: Kinetics and Mechanism of the Pyridinolysis of Alkyl Aryl Thionocarbonates.

✍ Scribed by E. A. CASTRO; M. CUBILLOS; J. G. SANTOS; J. TELLEZ

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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Kinetics and mechanism of the pyridinoly
Kinetics and mechanism of the pyridinolysis of benzenesulfonyl chlorides in methanol
✍ Sung Wan Hong; Han Joong Koh; Ikchoon Lee πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 65 KB πŸ‘ 2 views

The kinetics of reactions between Y-benzenesulfonyl chlorides and X-pyridines in methanol at 35.0 Β°C were investigated. Strong para p-acceptors, X = p-CN and p-COCH 3 , give good linear fits to BrΓΈnsted-type plots with low b X (=0.32-0.45) but show positive deviations from linear Hammett plots (& X