The kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0ΠC are studied. Relatively small values of β€ X (β€ nuc ) Ο 0.6 Ο³ 0.8 and β€ Z (β€ lg ) Ο Οͺ0.5 Ο³ Οͺ0.7 together with a negative cross-interaction constant XZ (Ο Οͺ0.47) and failure o
β¦ LIBER β¦
ChemInform Abstract: Kinetics and Mechanism of the Aminolysis of Thioesters and Thiocarbonates in Solution
β Scribed by Enrique A. Castro
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 11 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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