L@t rnoasurcments made during the afterglow oi pure nitrogen and helium-nitrogen mixtures indicate that mutual collisions of the N?(A 'XL) molecule are responsible for the formation of the Nz(C3n,) and Nz(C?nu) states. Results for the latter state arc in agreement with other workers. A value for th
Kinetics of excitation of N2(A3Σu+,vA), N2(C3
✍ Scribed by V. A. Shakhatov; Yu. A. Lebedev
- Book ID
- 110164654
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2008
- Tongue
- English
- Weight
- 593 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0018-1439
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N2(A'Z2:), the lowest electronically excited state of NZ, has a long and distinguished history due to its role in nitrogen discharges and the nitrogen afterglow. Recently, the production of N,(A) via photolysis and chemiluminescent reactions has been newly explored, and new facets of its reactivity
The excitation-transfer reaction N2(A 'Z: ) and CS molecules has been studied in a fast-flow reactor at 300 K; the excitation rate constant is (1.8';::) x10-l' cm3 molecule-' s-'. Excitation to the CS(a) state is favored over excitation to the Cs(a 'II) state. Excitation transfer from S( 'P) to S( '