𝔖 Bobbio Scriptorium
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Reactions of N2(A3Σ)

✍ Scribed by Michael F. Golde

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
918 KB
Volume
20
Category
Article
ISSN
0538-8066

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✦ Synopsis

N2(A'Z2:), the lowest electronically excited state of NZ, has a long and distinguished history due to its role in nitrogen discharges and the nitrogen afterglow. Recently, the production of N,(A) via photolysis and chemiluminescent reactions has been newly explored, and new facets of its reactivity have been uncovered. Nz(A) is unusual, in that its deactivation probability in collision with small molecules spans many orders of magnitude, and is frequently strongly dependent on the vibrational content of NJA). This behavior and the observed product channels can be understood in terms of a simple model for the energy transfer process. Brief comparison with reactions of related species is made.

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