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Kinetics and thermochemistry of the reactions of alkyl radicals (methyl, ethyl, isopropyl, sec-butyl, tert-butyl) with hydrogen iodide: a reconciliation of the alkyl radical heats of formation

✍ Scribed by Seetula, Jorma A.; Russell, John J.; Gutman, David

Book ID
121440974
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
974 KB
Volume
112
Category
Article
ISSN
0002-7863

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## Abstract A competitive method involving the direct measurement of radical concentrations by EPR spectroscopy has been used to show that in solution at 25Β°C the rate constants for the bimolecular self‐reactions of ethyl, isopropyl, __tert__‐butyl, cyclopentyl, and trichloromethyl are all approxim