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Photoelectron spectroscopy of methyl, ethyl, isopropyl, and tert-butyl radicals. Implications for the thermochemistry and structures of the radicals and their corresponding carbonium ions

✍ Scribed by Houle, F. A.; Beauchamp, J. L.

Book ID: 125977081
Publisher: American Chemical Society
Year: 1979
Tongue: English
Weight: 1008 KB
Volume: 101
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00509a010

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## Abstract A competitive method involving the direct measurement of radical concentrations by EPR spectroscopy has been used to show that in solution at 25°C the rate constants for the bimolecular self‐reactions of ethyl, isopropyl, __tert__‐butyl, cyclopentyl, and trichloromethyl are all approxim