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Kinetics and mechanism of the formation of alkyl radicals and alkyl(pentaaquo)chromium(2+) complexes by the reaction of free radicals derived from (2-hydroxy-2-propyl)(pentaaquo)chromium(2+) ions with alkyl iodides

✍ Scribed by Espenson, James H.; Bruhn, Suzanne L.; Bakac, Andreja

Book ID: 126332802
Publisher: American Chemical Society
Year: 1984
Tongue: English
Weight: 407 KB
Volume: 23
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00190a050

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✍ Roger Atkinson; Sara M. Aschmann; Arthur M. Winer 📂 Article 📅 1987 🏛 Springer Netherlands 🌐 English ⚖ 528 KB

Alkyl nitrate yields from the NO x photooxidations of neopentane, 2-methylbutane and 3-methylpentane have been determined over the temperature and pressure ranges 281-323 K and 54-740 tort, respectively. The formation of the alkyl nitrates is attributed to the reaction pathway and rate constant rat