✦ LIBER ✦

Alkyl nitrate formation from the reaction of a series of branched RO2radicals with NO as a function of temperature and pressure

✍ Scribed by Roger Atkinson; Sara M. Aschmann; Arthur M. Winer

Publisher: Springer Netherlands
Year: 1987
Tongue: English
Weight: 528 KB
Volume: 5
Category: Article
ISSN: 0167-7764
DOI: 10.1007/bf00192505

No coin nor oath required. For personal study only.

✦ Synopsis

Alkyl nitrate yields from the NO x photooxidations of neopentane, 2-methylbutane and 3-methylpentane have been determined over the temperature and pressure ranges 281-323 K and 54-740 tort, respectively. The formation of the alkyl nitrates is attributed to the reaction pathway

and rate constant ratios klb/(kla + klb) are estimated, where (la) is the reaction pathway

A method for estimating this rate constant ratio for primary, secondary and tertiary alkyl peroxy radicals is presented.

📜 SIMILAR VOLUMES

Formation of alkyl nitrates from the rea

Formation of alkyl nitrates from the reaction of branched and cyclic alkyl peroxy radicals with NO

✍ Roger Atkinson; Sara M. Aschmann; William P. L. Carter; Arthur M. Winer; James N 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 671 KB

The yields of C, and C, alkyl nitrates from neopentane, 2-methylbutane, 2-methylpentane, 3-methylpentane, and cyclohexane have been measured in irradiated CH30NO-NO-alkane-air mixtures at 298 t-2 K and 735-torr total pressure. Additionally, OH radical rate constants for neopentyl nitrate, 3-nitro-2-

A density functional theory study of N2O

A density functional theory study of N2O formation from the reaction of NO with pyridine and with acridine

✍ R. López; T.L. Sordo 📂 Article 📅 2004 🏛 Springer 🌐 English ⚖ 511 KB

Regioselectivity in the rhodium-catalyze

Regioselectivity in the rhodium-catalyzed hydroformylation of styrene as a function of reaction temperature and gas pressure

✍ Raffaello Lazzaroni; Andrea Raffaelli; Roberta Settambolo; Sergio Bertozzi; Giov 📂 Article 📅 1989 🏛 Elsevier Science ⚖ 504 KB

Kinetics of the reaction OH + NO + M → H

Kinetics of the reaction OH + NO + M → HONO + M as a function of temperature and pressure in the presence of argon, SF6, and N2 bath gas

✍ Steven Zabarnick 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 712 KB

A relative rate study of the reaction of

A relative rate study of the reaction of Cl atoms with a series of alkyl nitrates and nitro alkanes in air at 295 ± 2 K

✍ T. J. Wallington; M. M. Hinman; J. M. Andino; W. O. Siegl; S. M. Japar 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 389 KB 👁 1 views

## Abstract The relative rate technique has been used to measure rate constants for the reaction of chlorine atoms with nitro methane, nitro ethane, nitro propane, nitro butane, nitro pentane, ethyl nitrate, isopropyl nitrate, __n__‐propyl nitrate, 2‐pentyl nitrate, and 2‐heptyl nitrate. Decay rate

Mechanisms of the photochemical reaction

Mechanisms of the photochemical reaction of dimethyl diazomalonate with cyclohexene and methylcyclohexene as a function of temperature

✍ David S. Wulfman; Bruce Poling; Robert S. McDanlel Jr. 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 199 KB