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Regioselectivity in the rhodium-catalyzed hydroformylation of styrene as a function of reaction temperature and gas pressure

✍ Scribed by Raffaello Lazzaroni; Andrea Raffaelli; Roberta Settambolo; Sergio Bertozzi; Giovanni Vitulli

Publisher: Elsevier Science
Year: 1989
Weight: 504 KB
Volume: 50
Category: Article
ISSN: 0304-5102
DOI: 10.1016/0304-5102(89)80104-x

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## Abstract Rate constants for the gas‐phase reactions of the hydroxyl radical with the biogenic hydrocarbons, β‐myrcene and isoprene, were measured using the relative rate technique over the temperature range 313–413 K and at ∼1 atm total pressure. OH was produced by the photolysis of H~2~O~2~, an