The kinetics of the reactions of 10, BrO, and C10 with DMS have been investigated at 298 K and total pressures of 0.5-6.8 mbar He using the discharge flow-mass spectrometry technique to monitor the halogen oxide radicals. Rate coefficients of (8.8 (2.7 f 0.5) x cm3 molecule-' 8-l have been obtained
Kinetics and product studies of the BrO + ClO Reaction: Implications for Antarctic chemistry
β Scribed by Sander, Stanley P.; Friedl, Randall R.
- Book ID
- 119708314
- Publisher
- American Geophysical Union
- Year
- 1988
- Tongue
- English
- Weight
- 370 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1944-8007
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π SIMILAR VOLUMES
## Abstract The rates of several novel elementary reactions involving ClO, BrO and SO free radicals in their ground states were studied in a dischargeβflow system at 295 K, using mass spectrometry. The rate constant __k__~2~ was determined from the decay of SO radicals in the presence of excess ClO
The reaction between BrO and HOs radicals: BrO + HO2 +HOBr + O2 ( 1 a) + HBr t 0s ( 1 b) was investigated using flash photolysis with UV absorption detection of the radicals, at 298 K and 760 Torr total pressure. BrO and HO1 radicals were formed in the flash photolysis of Br~/O,/Cl,/CH,OH/O,/He mixt