Kinetics and Mechanism of the BrO Self-Reaction: Temperature- and Pressure-Dependent Studies
โ Scribed by Harwood, Matthew H.; Rowley, David M.; Cox, R. Anthony; Jones, Roderic L.
- Book ID
- 126842378
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 166 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
A laser flash photolysis-long path absorption technique has been employed to study the kinetics of the reaction BrO + NO2 + M Q products as a function of temperature (248-346 K), pressure (16-800 torr), and buffer gas identity (N2, CF4). The reaction is found to be in the falloff regime between thir
The reaction between BrO and HOs radicals: BrO + HO2 +HOBr + O2 ( 1 a) + HBr t 0s ( 1 b) was investigated using flash photolysis with UV absorption detection of the radicals, at 298 K and 760 Torr total pressure. BrO and HO1 radicals were formed in the flash photolysis of Br~/O,/Cl,/CH,OH/O,/He mixt