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Kinetic studies of the reactions of BrO and IO radicals

✍ Scribed by Laszlo, Barna; Huie, Robert E.; Kurylo, Michael J.; Miziolek, Andrzej W.


Book ID
118669349
Publisher
American Geophysical Union
Year
1997
Tongue
English
Weight
869 KB
Volume
102
Category
Article
ISSN
0148-0227

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πŸ“œ SIMILAR VOLUMES


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The kinetics and mechanism of the reaction of BrO with dimethylsulfide [ DMS) have been studied by the mass spectrometric discharge-flow method in the temperature range (233-320) K and at a total pressure around 1 torr. The temperature dependence of the reaction rate constant k , = [ 1.5 ? 0 4 ) X 1

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The reaction between BrO and HOs radicals: BrO + HO2 +HOBr + O2 ( 1 a) + HBr t 0s ( 1 b) was investigated using flash photolysis with UV absorption detection of the radicals, at 298 K and 760 Torr total pressure. BrO and HO1 radicals were formed in the flash photolysis of Br~/O,/Cl,/CH,OH/O,/He mixt